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Class 12 · Chemistry

For molar-mass determination of a non-electrolyte solute, which statement is correct?

Class 12 · Chemistry

If a solute completely dissociates into three ions in solution, how will its apparent molar mass compare with its true molar mass?

Class 12 · Chemistry

A solute has a true molar mass of 60 g mol⁻¹, but freezing-point depression gives an apparent molar mass of 30 g mol⁻¹. What is the van’t Hoff factor?

Class 12 · Chemistry

Which method often needs very precise measurement because the temperature change is very small?

Class 12 · Chemistry

If the molar mass of an acid in benzene, determined from freezing-point depression, is nearly double the expected value, what does it indicate?

Class 12 · Chemistry

Which assumption is necessary while determining molar mass by relative lowering of vapour pressure?

Class 12 · Chemistry

In the osmotic-pressure method, using M = wRT/(πV), what does V represent?

Class 12 · Chemistry

1.5 g of a non-volatile solute dissolved in 50 g of benzene raises its boiling point by 0.78 K. If Kb for benzene is 2.6 K kg mol⁻¹, what is the molar mass of the solute?

Class 12 · Chemistry

If 2 g of a solute dissolved in 100 g of water lowers the freezing point by 0.186 K, and Kf for water is 1.86 K kg mol⁻¹, what is the molar mass of the solute?

Class 12 · Chemistry

Why is the osmotic-pressure method considered especially useful for determining the molar mass of biomolecules?

Class 12 · Chemistry

Equal masses of two non-volatile solutes are dissolved in equal masses of the same solvent. If the first solution shows a greater freezing-point depression, what can be concluded about the first solute?

Class 12 · Chemistry

In the freezing-point depression method, in which situation will the calculated molar mass of a solute be higher than its true value?

Class 12 · Chemistry

The molar mass of a solute determined by osmotic pressure is lower than its normal value. What is the most suitable reason?

Class 12 · Chemistry

The molar mass of an unknown non-volatile solute is determined using boiling-point elevation. If the solvent mass is halved while the solute mass remains unchanged, what happens to the elevation?

Class 12 · Chemistry

In molar mass determination, if the observed van’t Hoff factor is i < 1, what is the most suitable conclusion?

Class 12 · Chemistry

A 1 L solution is prepared from 3.6 g of a solute. At 300 K, its osmotic pressure is 0.369 atm. If the solute undergoes 25% dimerization, what is its approximate true molar mass?

Class 12 · Chemistry

An AB₂ solute has a van’t Hoff factor of 2.6, and its true molar mass is 156 g mol⁻¹. What are its observed molar mass and degree of dissociation?

Class 12 · Chemistry

When 0.5 g of a solute is dissolved in 250 g of water, the freezing-point depression is 0.0186 K. If i = 1 and Kf for water is 1.86 K kg mol⁻¹, what is the molar mass?

Class 12 · Chemistry

If a solute has i = 0.4 and a true molar mass of 80 g mol⁻¹, what will be the observed molar mass determined by a colligative method?

Class 12 · Chemistry

An AB solute has a van’t Hoff factor i = 1.25 and an observed molar mass of 96 g mol⁻¹. What are its true molar mass and degree of dissociation?