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In Class 12 Chemistry, Chapter 01: Solutions, students learn how solutions are classified according to the physical states of their solute and solvent. The topic explains gaseous, liquid, and solid solutions, with familiar examples such as air, salt water, and alloys. It also helps learners distinguish solutions by composition and understand how the identity and relative amounts of the components determine the type of solution formed.
Practice questions
01 Why can identifying the solvent be difficult when two liquids are mixed in nearly equal amounts?
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Answer and explanation
Correct answer: A. Because the difference in amount is not clear
Explanation: The solvent is usually the component present in larger amount, or the component that provides the medium. When two liquids are present in nearly equal quantities, the larger-amount rule gives no clear answer, so the question’s stated convention or context must be used. Liquids can certainly form solutions.
02 Which option gives a correct example of a liquid solute and a solid solvent?
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Answer and explanation
Correct answer: A. Mercury amalgam in a metal
Explanation: Mercury is liquid at ordinary conditions, and an amalgam is formed when mercury is incorporated into a metal. When the metal acts as the solid solvent, this represents liquid in solid solution. Sugar in water is solid in liquid, oxygen in air is gas in gas, and carbon dioxide in water is gas in liquid.
03 If water remains the solvent, when does the physical type of the solution remain unchanged despite a change in solute amount?
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Answer and explanation
Correct answer: A. If the solvent remains liquid, the solution remains a liquid solution
Explanation: The overall physical state of an ordinary solution follows the state of its solvent. If water remains the liquid solvent, adding a smaller or larger amount of dissolved solute does not by itself turn the solution into a solid or gas. Amount affects concentration, not the basic state classification, unless a phase change actually occurs.
04 A student said that every liquid mixture is a liquid-liquid solution. What is the correct correction?
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Answer and explanation
Correct answer: A. Only uniformly miscible liquids form liquid-liquid solutions
Explanation: A liquid-liquid solution requires two liquids to be miscible and form a homogeneous single phase. If the liquids remain in separate layers, as water and oil do, the mixture is not a true liquid-liquid solution. A liquid can act as either solute or solvent, and a gas is not required in this type of solution.
05 Which statement correctly explains the difference between solid in liquid and liquid in solid?
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Answer and explanation
Correct answer: B. In solid in liquid solvent is liquid, in liquid in solid solvent is solid
Explanation: In a solid-in-liquid solution, the solute is solid and the solvent is liquid; salt dissolved in water is a familiar example. In a liquid-in-solid solution, the solute is liquid while the solvent is solid, as in some metal–mercury systems. The phrase before “in” names the solute and the phrase after it names the solvent. Therefore B is correct.
06 In which example can both state-based and number-based classifications be understood together?
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Answer and explanation
Correct answer: A. Salt in water
Explanation: Salt in water contains two components: salt and water, so it is a binary solution when classified by the number of components. It is also a solid-in-liquid solution because salt is the solid solute and water is the liquid solvent. The other choices are pure substances rather than solutions, so they do not provide both classifications in this context.
07 If two metals are uniformly mixed in solid state and one of them is present in larger amount, how will the solvent be identified?
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Answer and explanation
Correct answer: A. The metal present in larger amount will be considered the solvent
Explanation: In a homogeneous alloy, the component present in the larger proportion is conventionally treated as the solvent or continuous medium, while the smaller component is the solute. Since the two metals are uniformly mixed, the system can be regarded as a solid solution. Separate layers would indicate heterogeneity, and a solution need not contain a liquid. Thus the larger-amount metal is the solvent, so A is correct.
08 A homogeneous mixture has a gaseous solute and a solid solvent. What is the most correct name of this mixture?
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Answer and explanation
Correct answer: B. Gas in solid solution
Explanation: The naming convention states the solute first and the solvent second. Here the solute is gaseous and the solvent is solid, so the correct description is gas in solid solution. The final state is solid because the solvent is solid. Options A, C, and D either reverse the roles or use the wrong solvent state. Therefore B is the only consistent answer.
09 What is the scientific basis for considering air a gaseous solution?
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Answer and explanation
Correct answer: B. Its main solvent is gaseous and other gases are uniformly mixed
Explanation: Air is a homogeneous mixture of several gases. Nitrogen, its major component, is conventionally treated as the solvent, while oxygen and other gases act as solutes. Because the continuous medium is gaseous and the components are uniformly distributed, air is classified as a gaseous solution. Separate layers, one gas only, or sediment would contradict this description. Therefore B is correct.
10 In a solution, water is present in smaller amount and alcohol in larger amount. Both liquids are completely mixed. According to the general rule, which is the solvent?
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Answer and explanation
Correct answer: B. Alcohol
Explanation: When two completely miscible liquids form a solution, the component present in the larger amount is generally treated as the solvent and the smaller-amount component as the solute. Since alcohol is present in greater amount here, alcohol is the solvent and water is the solute. Water is not automatically the solvent merely because it is common or familiar. Therefore B is correct.
11 A student said that in a solid solution the solute will always be solid. Which example disproves this idea?
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Answer and explanation
Correct answer: B. Hydrogen in palladium
Explanation: The state-based name of a solution is determined by the solvent, not necessarily by the solute. In hydrogen dissolved in palladium, palladium is the solid solvent, while hydrogen is a gaseous solute; this is therefore a solid solution containing a gas solute. Brass has solid components, salt water has a liquid solvent, and air has a gaseous solvent, so they do not demonstrate the required point as directly.
12 Which option is an example of a liquid solution in which the solute is a gas?
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Answer and explanation
Correct answer: B. Carbon dioxide in water
Explanation: In carbon dioxide dissolved in water, carbon dioxide is the gaseous solute and water is the liquid solvent. Because the solvent is liquid, the overall solution is classified as a liquid solution, specifically gas in liquid. Salt water is solid in liquid, water–ethanol is liquid in liquid, and brass is a solid solution, so they do not meet both conditions in the question.
13 Salt water and soda water are both liquid solutions. What is the main difference between them?
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Answer and explanation
Correct answer: A. Salt water has a solid solute and soda water has a gaseous solute
Explanation: Both systems have liquid water as their solvent, so both are liquid solutions. In salt water, the solute is solid sodium chloride. In soda water, dissolved carbon dioxide is the gaseous solute. Thus the solvent state is the same, but the solute states differ. Options B, C, and D either misidentify the solute or the solution state. Therefore A is correct.
14 Which statement correctly describes an amalgam?
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Answer and explanation
Correct answer: B. It may be a liquid-solid or solid solution involving mercury and a metal
Explanation: An amalgam is an alloy or solution involving mercury and another metal. Mercury is liquid at ordinary temperature, while the other metal may be solid; depending on composition, the resulting amalgam can be liquid or solid. Many amalgams are homogeneous solutions, although not every mercury–metal system has the same phase. It is not a gas mixture and does not require water. Hence B is correct.
15 Which option has solute and solvent in different states but the solution is liquid?
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Answer and explanation
Correct answer: C. Oxygen in water
Explanation: In oxygen dissolved in water, oxygen is a gas and water is a liquid, so the solute and solvent have different states. Since water is the solvent and remains the continuous phase, the solution is classified as a liquid solution, specifically gas in liquid. Air is gas in gas, brass is solid in solid, and water–ethanol has two liquid components, so they do not satisfy both conditions.
16 Which option has water present but it cannot definitely be considered the solvent?
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Answer and explanation
Correct answer: A. When water is in smaller amount and another liquid is in larger amount
Explanation: Water is commonly a solvent, but its presence alone does not guarantee that role. When water is the smaller-amount component and another completely miscible liquid is present in larger amount, the other liquid is generally treated as the solvent and water may be the solute. In the other examples, the wording explicitly places salt, sugar, or oxygen in water, making water the solvent. Hence A is correct.
17 In which pair do both examples have a liquid solvent but different solute states?
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Answer and explanation
Correct answer: A. Salt water and soda water
Explanation: Salt water has liquid water as the solvent and solid salt as the solute. Soda water also has liquid water as the solvent, but its solute is gaseous carbon dioxide. Thus both examples have liquid solvents while their solutes have different states. Brass has a solid solvent, air has a gaseous solvent, and hydrogen in palladium has a solid solvent, so the other pairs fail the first condition.
18 A solution has both solute and solvent as liquids, but the solution is non-aqueous. Which example is suitable?
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Answer and explanation
Correct answer: B. A liquid substance uniformly mixed in alcohol
Explanation: A liquid–liquid solution requires both components to be liquids and uniformly mixed. It is non-aqueous when the solvent is not water. In option B, alcohol is the liquid solvent and another liquid is uniformly dissolved or mixed in it, so the example satisfies both conditions. The water-based examples are aqueous, while oxygen in air is gas in gas. Therefore B is correct.
19 If a sample is filtered and the solute does not separate, and every part remains uniform, which explanation is more appropriate?
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Answer and explanation
Correct answer: A. It is a homogeneous mixture like a true solution
Explanation: In a true solution, solute particles are molecular or ionic in scale and pass through ordinary filter paper, so filtration does not separate them. The solution also remains uniform throughout because it is homogeneous. These observations support identification as a true-solution-like homogeneous mixture. Sedimentation or visible separation would suggest a heterogeneous system, and every solution has a solvent. Thus A is correct.
20 Which option gives the solute states in the order solid, gas, and liquid?
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Answer and explanation
Correct answer: A. Salt in water, carbon dioxide in water, mercury in metal
Explanation: In salt water, salt is the solid solute. In carbon dioxide dissolved in water, carbon dioxide is the gaseous solute. In a metal–mercury solution, mercury is the liquid solute while the metal is the solvent. Therefore the solute-state sequence is solid, gas, liquid, exactly as required in option A. The other sequences begin with gas or use mismatched examples.
21 In which case is memorizing the example alone not enough?
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Answer and explanation
Correct answer: A. When the question changes solute and solvent roles
Explanation: Memorizing isolated examples can cause errors when a question changes the order or roles of the components. The learner should first identify which substance is the solute and which is the solvent, then note their physical states and the number of components. This method works for familiar and unfamiliar examples, unlike simple recall.
22 Which statement gives the correct understanding of an alloy?
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Answer and explanation
Correct answer: A. It can be a homogeneous solid solution
Explanation: An alloy is a mixture of elements, usually metals, made by combining them in the liquid state and obtaining a solid material on cooling. When its components are uniformly distributed, it is treated as a homogeneous solid solution; brass is a familiar example. An alloy is not necessarily aqueous or gaseous, and its components do mix.
23 Which option does not correctly show solute and solvent roles?
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Answer and explanation
Correct answer: D. In hydrogen in palladium palladium is solute
Explanation: In hydrogen dissolved in palladium, palladium forms the continuous solid medium and is therefore the solvent; hydrogen is the solute. Thus option D reverses their roles. In soda water, water is the solvent; in salt water, salt is the solute; and in air, nitrogen is commonly treated as the major solvent because it is present in greatest proportion.
24 If a solution is described only as binary, which information is still needed to classify its physical state?
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Answer and explanation
Correct answer: A. The physical states of the components
Explanation: The term binary gives only one fact: the solution contains two components, usually a solute and a solvent. It does not tell whether the solvent is solid, liquid, or gas, nor does it by itself reveal the physical state of the solute or the final solution. The physical states of the components are therefore needed for classification. Options B and C merely repeat the meaning of binary.
25 If a solution is described only as liquid, what information is still needed?
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Answer and explanation
Correct answer: A. State of solute
Explanation: Calling the solution liquid generally indicates that its solvent is liquid, but it does not identify the state of the solute. The solute may be solid, liquid, or gas, producing solid-in-liquid, liquid-in-liquid, or gas-in-liquid solutions. Therefore the solute state is the missing information needed for the complete type.
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