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In an aqueous solution the mole fraction of water is 0.90. What is the approximate molality of the solute?

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Answer and explanation

Correct answer: 6.17 mol kg−1

The mole fractions of solute and water sum to one. Thus, if xwater = 0.90, xsolute = 0.10. Take 1 mol total mixture: water = 0.90 mol and solute = 0.10 mol. Water mass = 0.90 × 18 = 16.2 g = 0.0162 kg. Molality = 0.10/0.0162 ≈ 6.17 mol kg−1, so option B is correct. The denominator must be solvent mass, not total solution mass.

Tags

mole fractionmolalityaqueous solutionsolvent massMole concept and molar massSome Basic Concepts of ChemistryChemistryClass 11 MCQ

Frequently asked questions

What is the correct answer to this question?

6.17 mol kg−1

Why is this the correct answer?

The mole fractions of solute and water sum to one. Thus, if xwater = 0.90, xsolute = 0.10. Take 1 mol total mixture: water = 0.90 mol and solute = 0.10 mol. Water mass = 0.90 × 18 = 16.2 g = 0.0162 kg. Molality = 0.10/0.0162 ≈ 6.17 mol kg−1, so option B is correct. The denominator must be solvent mass, not total solution mass.

Which subject and chapter does this question cover?

This is a Class 11 Chemistry question. Chapter: Some Basic Concepts of Chemistry. Topic: Mole concept and molar mass.

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