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What is the approximate molality of a 68 percent by mass aqueous nitric acid solution?

Answer and explanation

Correct answer: 33.7 mol kg−1

Molality uses kilograms of solvent, not kilograms of the entire solution. Choose 100 g solution: 68 g is HNO3 and 32 g is water. Moles of HNO3 = 68/63 ≈ 1.079 mol, while solvent mass = 32 g = 0.032 kg. Hence molality = 1.079/0.032 ≈ 33.7 mol kg−1, so option C is correct. Dividing by 0.100 kg would incorrectly use solution mass and produce a different concentration.

Related tags

Mass PercentMolalityNitric AcidConcentrationMole Concept And Molar MassSome Basic Concepts Of ChemistryChemistryClass 11 Mcq

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